Top rated Books / Libraries are as follows
Learn to Program with Visual Basic and .NET Gadgeteer
This book is intended for school students and others learning to program in Visual Basic. It assumes no prior knowledge of programming, electronics, Visual Basic or the Visual Studio environment. Concepts are introduced and explained throughout the book.
Visual Basic Essentials (Neil Smyth)
This book is intended to be of use to both novices looking to learn Visual Basic, and to those proficient in other languages to learn Visual Basic.
Introduction: Visual BASIC 6.0 (Gary Haggard, et al)
This book provides a hands-on introduction to all aspects of application development with Visual Basic. Each component is covered in the context of using Visual Basic to develop Windows-based, client/server production business applications.
Learn Visual Basic 6.0 (Lou Tylee)
This book teaches Visual Basic in a straightforward manner. Whether you want to build original programs from the ground up or take advantage of existing wizards, this book will help you design and debug your work - and accomplish all your goals!